Chemistry of sunblock
Sunblock is designed to protect you from UV
radiation from the sun, which is a shorter wavelength than the visible light, by forming a physical shield.
Major of the energy emitted by the sun is in the form of UV radiations, and it
can be divided into three categories, including UVC, UVA, and UVB radiations.
Ozone in the atmosphere absorbs all UVC before it reaches the Earth’s surface,
and it approximately absorbs 90% of UVB radiation. However, UVA radiation is
less affected by the atmosphere. Therefore, both UVA and UVB cause damage to
the skin, in which UVA causes aging while UVB causes burning. Each type of UV
radiation has a different wavelength; the longest wavelength is UVA radiation,
which can reach to 400nm.
In the past, the Egyptians used ingredients,
such as rice bran, jasmine, and lupine to ensure sun protection, whereas the
ancient Greeks used olive oil. Nowadays, both inorganic chemicals and organic chemicals
are ingredients in sun protection products. The two inorganic compounds used
are titanium dioxide and zinc oxide. The first sunblock contains only these
chemicals, which act as a physical sun protectant, making a barrier against the
damaging rays of the sun by scattering and reflecting them away from the skin. As
a result, physical UV protection products leave a visible white layer on the
skin. On the other hand, sunscreen is a term that describes either a physical
or chemical sun product, which absorbs the UV rays.
Sunscreen is used; it is a combination of
inorganic chemicals with organic chemicals. Due to the chemical structures and
chemical bonds in certain organic chemicals, they are able to absorb photons of
the UV light. Then, this energy is dissipated harmlessly in the form of heat. Therefore,
a mix of organic chemicals, which can absorb different wavelengths, is used in
order to ensure protection against the full range of UVA and UVB wavelengths. Organic
chemicals are, for example, octyl methoxycinnamate, octyl salicylate,
octocrylene, and ecamsule.
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